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Beilstein J. Org. Chem. 2010, 6, 810–822, doi:10.3762/bjoc.6.91
Graphical Abstract
Figure 1: The photoaffinity technique allows the identification of ligand binding sites of a receptor protein...
Figure 2: a) Three known photolabile α-D-mannosides that differ in the nature of the photoactive functional g...
Scheme 1: Synthesis of photoactive glycoamino acids 11 and 12. i) Fmoc-Asp-OtBu (for 7), Fmoc-Asp(OtBu)-OH (f...
Scheme 2: Photo-crosslinking experiments with the model peptide angiotensin II and the photoactive mannosides ...
Figure 3: Affino dot–blot with FimHtr and photoactive mannosides applied to nitrocellulose disks. It was irra...
Figure 4: MS/MS spectra of angiotensin II (a) and of angiotensin II, photo-crosslinked with diazirine 2 (b), ...
Beilstein J. Org. Chem. 2010, 6, 801–809, doi:10.3762/bjoc.6.90
Figure 1: a) Connolly surface of FimH in complex with FimC [8]. The CRD known from X-ray structures at the tip o...
Figure 2: The bivalent glycopeptide 1 is the target molecule to test the hypothesis of two carbohydrate bindi...
Scheme 1: Synthesis of the eastern part of target molecule 1.
Scheme 2: Synthesis of the western part of target molecule 1.
Scheme 3: Synthesis of the target molecule 1 employing squaric acid diethylester (DES).